Inorganic Solid Phases

[Ag4{S(NSO)2}9][AsF6]4·SO2 (Ag2As2S14[NSO]9F12[SO2]) Crystal Structure

General Information

  • Phase Label(s): Ag2As2S14[NSO]9F12[SO2]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR594
  • Space Group: 161
  • Phase Prototype: Ag4As4S9[NSO]18F24[SO2]
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Siemens-STOE (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): sulfinylamide, fluoride, sulfide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 1653 reflections; F > 4σ(F), R = 0.070; wR = 0.070
  • Sample Detail(s): sample prepared from AgAsF6, S[NSO]2, chemical analysis; 16.8 wt.% F, 10.3 wt.% N, single crystal (determination of cell parameters), single crystal, 0.23×0.45×0.50 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Ag4As4S9[NSO]18F24[SO2]
  • Alphabetic Formula: Ag4As4F24[NSO]18S9[SO2]
  • Published Formula: [Ag4{S(NSO)2}9][AsF6]4·SO2
  • Refined Formula: Ag4As4F24N18O20S28
  • Wyckoff Sequence: 161,b32a3
  • Z Formula Units: 6
  • Density: ρ = 2.55 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1004485

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied