Inorganic Solid Phases

K5H[SiMnMo2W9O40]·11H2O (HK5W9Mo2Mn[SiO4]O36[H2O]11) Crystal Structure

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General Information

  • Phase Label(s): HK5W9Mo2Mn[SiO4]O36[H2O]11
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: mP138
  • Space Group: 4
  • Phase Prototype: HK5W9Mo2Mn[SiO4]O36[H2O]11
  • Measurement Detail(s): automatic diffractometer; Siemens P4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of structural parameters)
  • Phase Class(es): –
  • Compound Class(es): orthosilicate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 4330 reflections, R = 0.0666; wR = 0.08655
  • Sample Detail(s): sample prepared from MnSO4[H2O]2, α-K8[SiW9Mo2O39][H2O]20, KCl, atomic absorption spectroscopy, atomic emission spectroscopy, thermogravimetry; 55.65 wt.% W, 8.52 wt.% H2O, 6.39 wt.% K, 6.14 wt.% Mo, 1.65 wt.% Mn, single crystal, 0.34×0.42×0.50 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: HK5W9Mo2Mn[SiO4]O36[H2O]11
  • Alphabetic Formula: H[H2O]11K5MnMo2O36[SiO4]W9
  • Published Formula: K5H[SiMnMo2W9O40]·11H2O
  • Refined Formula: H22K5MnMo2O51SiW9
  • Wyckoff Sequence: 4,a69
  • Z Formula Units: 2
  • Density: ρ = 3.47 Mg·m−3
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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1020334

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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