Inorganic Solid Phases

Cs2Na8[(α-AsW9O33)2WO(H2O)Zn2(H2O)2]·23H2O (Cs2Na8Zn2W19As2O67[H2O]26, T = 173 K) Crystal Structure

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General Information

  • Phase Label(s): Cs2Na8Zn2W19As2O67[H2O]26
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: mP274
  • Space Group: 11
  • Phase Prototype: Cs2Na8(Zn0.67W0.33)3W18As2O67[H2O]26
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Siemens SMART (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 173 K (determination of cell and structural parameters)
  • Phase Class(es): –
  • Compound Class(es): oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 8653 reflections, R = 0.051; wR = 0.129
  • Sample Detail(s): sample prepared from ZnCl2, Na9[AsW9O33][H2O]19.5, CsCl, chemical analysis; 4.67 wt.% Cs, 3.39 wt.% Na, 58.05 wt.% W, 2.77 wt.% Zn, 2.70 wt.% As, single crystal (determination of cell parameters), single crystal, 0.12×0.12×0.10 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Cs2Na8Zn2W19As2O67[H2O]26
  • Alphabetic Formula: As2Cs2[H2O]26Na8O67W19Zn2
  • Published Formula: Cs2Na8[(α-AsW9O33)2WO(H2O)Zn2(H2O)2]·23H2O
  • Refined Formula: As2Cs2H52Na3O92W18.70Zn2.30
  • Wyckoff Sequence: 11,f57e23
  • Z Formula Units: 2
  • Density: ρ = 4.12 Mg·m−3
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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1110843

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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