Inorganic Solid Phases

Hg_0.7Pb_0.3Ba₂Ca₂Cu₃O_8+d (Ba₂Ca₂Cu₃Hg_0.62Pb_0.38O_8.35) Crystal Structure

Get Access CIF Download help (pdf)

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

General Information

Phase Label(s): Ba₂Ca₂Cu₃Hg_0.62Pb_0.38O_8.35
Structure Class(es): high-T_c cuprate family
Classification by Properties: diamagnetic, high-T_c superconductor, metal
Mineral Name(s): –
Pearson Symbol: tP17
Space Group: 123
Phase Prototype: Ba₂Ca₂Cu₃HgO_8.44
Measurement Detail(s): automatic diffractometer (determination of cell and structural parameters), neutrons; λ = 0.1541 nm (determination of cell and structural parameters)
Phase Class(es): –
Compound Class(es): oxide
Interpretation Detail(s): complete structure determined, Rietveld refinement, multiphase, R_P = 0.0835; wR_P = 0.1089; R_B = 0.0840
Sample Detail(s): sample prepared from HgO, PbO, Ba₂Ca₂Cu₃O₇, nominal composition Ba₂Ca₂Cu₃Hg_0.7Pb_0.3O_8+d; amounts of CaHgO₂ and BaCuO₂, powder (determination of cell and structural parameters)

Substance Summary

Standard Formula: Ba₂Ca₂Cu₃Hg_0.618Pb_0.382O_8.45
Alphabetic Formula: Ba₂Ca₂Cu₃Hg_0.618O_8.45Pb_0.382
Published Formula: Hg_0.7Pb_0.3Ba₂Ca₂Cu₃O_8+d
Refined Formula: Ba₂Ca₂Cu₃Hg_0.62O_8.45Pb_0.38
Wyckoff Sequence: 123,ih²g²ecba
Z Formula Units: 1
Density: ρ = 6.27 Mg·m⁻³

View 3D Interactive Structure

Cite this page

Citation

Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
Space Group	Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Displacement Parameters

Isotropic

Site	Published B [nm²]	Type	Computed B_eq [nm²]
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Experimental Details

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

Reference

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

3D Interactive Structure

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1123172

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials Hg0.7Pb0.3Ba2Ca2Cu3O8+d (Ba2Ca2Cu3Hg0.62Pb0.38O8.35) Crystal Structure sd_1123172 (Springer-Verlag GmbH, Heidelberg, © 2016)

Download this citation

Citation copied