Inorganic Solid Phases

LiBi_7.37P₃O₁₉, LiBi_7.3P₃O₁₉ (Li₂Bi_14.7[PO₄]₆O₁₄) Crystal Structure

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General Information

Phase Label(s): Li₂Bi_14.7[PO₄]₆O₁₄
Structure Class(es): –
Classification by Properties: –
Mineral Name(s): –
Pearson Symbol: mS244
Space Group: 15
Phase Prototype: Li₂Bi_14.7[PO₄]₆O₁₄
Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Nonius (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
Phase Class(es): –
Compound Class(es): orthophosphate, oxide
Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 164 variables; 3337 reflections; I > 2σ(I), R = 0.049; wR = 0.134
Sample Detail(s): sample prepared from Bi₂O₃, NH₄H₂PO₄, Li₂CO₃, spectroscopy; Bi/Li ratio 6.73/1.2, single crystal (determination of cell parameters), single crystal, 0.03×0.05×0.10 mm³ (determination of structural parameters)

Substance Summary

Standard Formula: Li₂Bi_14.7[PO₄]₆O₁₄
Alphabetic Formula: Bi_14.7Li₂O₁₄[PO₄]₆
Published Formula: LiBi_7.37P₃O₁₉, LiBi_7.3P₃O₁₉
Refined Formula: Bi_14.74Li₂O₃₈P₆
Wyckoff Sequence: 15,f³⁰e
Z Formula Units: 4
Density: ρ = 7.67 Mg·m⁻³

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Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
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a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
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Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
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Displacement Parameters

Isotropic

Site	Published U [nm²]	Type	Computed B_eq [nm²]
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Anisotropic

Site	U₁₁ [nm²]	U₂₂ [nm²]	U₃₃ [nm²]	U₁₂ [nm²]	U₁₃ [nm²]	U₂₃ [nm²]
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Experimental Details

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Reference

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3D Interactive Structure

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About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1123551

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials LiBi7.37P3O19, LiBi7.3P3O19 (Li2Bi14.7[PO4]6O14) Crystal Structure sd_1123551 (Springer-Verlag GmbH, Heidelberg, © 2016)

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