Inorganic Solid Phases

K0.27Co[Fe(CN)6]0.73[D2O]0.27·1.42D2O (K0.27Fe0.73Co[CN]4.38[D2O]1.69, T = 40 K) Crystal Structure

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General Information

  • Phase Label(s): K0.27Fe0.73Co[CN]4.38[D2O]1.69
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: cF88
  • Space Group: 225
  • Phase Prototype: CdFe0.67[CN]4[H2O]3.33
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; U.S.A. Tennessee, Oak Ridge National Laboratory ORNL, HFIR (determination of structural parameters), neutrons; λ = 0.241 nm (determination of cell and structural parameters), T = 40 K (determination of cell and structural parameters)
  • Phase Class(es): –
  • Compound Class(es): cyanide, hydrate-D
  • Interpretation Detail(s): complete structure determined, Rietveld refinement
  • Sample Detail(s): sample prepared from KNO3, K3(Fe[CN]6), CoCl2, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: K0.27Fe0.73Co[CN]4.38[D2O]1.69
  • Alphabetic Formula: [CN]4.38Co[D2O]1.69Fe0.73K0.27
  • Published Formula: K0.27Co[Fe(CN)6]0.73[D2O]0.27·1.42D2O
  • Refined Formula: C4.38CoD3.24Fe0.73K0.27N4.38O1.62
  • Wyckoff Sequence: 225,e3cba
  • Z Formula Units: 4
  • Density: ρ = 1.60 Mg·m−3
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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1128301

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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