Inorganic Solid Phases

Na12Rb[Th33-O)(μ2-OH)3(SiW9O34)2] (RbNa12Th3W18[SiO4]2O61[OH]3[H2O]26, T = 100 K) Crystal Structure

General Information

  • Phase Label(s): RbNa12Th3W18[SiO4]2O61[OH]3[H2O]26
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hP282
  • Space Group: 176
  • Phase Prototype: RbNa12Th3W18[SiO4]2O61[OH]3[H2O]26
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS X8 SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 100 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthosilicate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 218 variables; 5258 reflections; I > 2σ(I), R = 0.0331; wR = 0.0694
  • Sample Detail(s): sample prepared from Na10[SiW9O34][H2O]12, Th(NO3)4·4H2O, RbNO3, energy-dispersive X-ray analysis; Na/Rb/Th/W ratio 9.7/0.47/3.98/18, single crystal (determination of cell parameters), single crystal, 0.15×0.15×0.30 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: RbNa12Th3W18[SiO4]2O61[OH]3[H2O]26
  • Alphabetic Formula: [H2O]26[OH]3[SiO4]2Na12O61RbTh3W18
  • Published Formula: Na12Rb[Th33-O)(μ2-OH)3(SiW9O34)2]
  • Refined Formula: H55Na12O98RbSi2Th3W18
  • Wyckoff Sequence: 176,i20h3f3e2cb
  • Z Formula Units: 2
  • Density: ρ = 4.71 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1142970

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied