H96K4Tb4W20.88Mo3.12O128 (H2KTbW5.22Mo0.78O21[H2O]11) Crystal Structure
General Information
- Phase Label(s): H2KTbW5.22Mo0.78O21[H2O]11
- Structure Class(es): –
- Classification by Properties: –
- Mineral Name(s): –
- Pearson Symbol: mP160
- Space Group: 14
- Phase Prototype: H2KLaW4(W0.60Mo0.30)2O21[H2O]10
- Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Siemens (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 298(2) K (determination of cell and structural parameters)
- Phase Class(es): –
- Compound Class(es): oxide, hydrate
- Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 363 variables; 4685 reflections, R = 0.0556; wR = 0.1178
- Sample Detail(s): sample prepared from Na2WO4[H2O]2, [NH4]6Mo7O24[H2O]4, Al2[SO4]3[H2O]18, Tb3+, HCl, chemical analysis, spectroscopy; 2.23 wt.% K, 8.96 wt.% Tb, 54.26 wt.% W, 4.27 wt.% Mo, single crystal (determination of cell parameters), single crystal, 0.06×0.08×0.16 mm3 (determination of structural parameters)
Substance Summary
- Standard Formula: H2KTbW5.22Mo0.78O21[H2O]11
- Alphabetic Formula: H2[H2O]11KMo0.78O21TbW5.22
- Published Formula: H96K4Tb4W20.88Mo3.12O128
- Refined Formula: KMo0.78O32TbW5.22
- Wyckoff Sequence: 14,e40
- Z Formula Units: 4
- Density: ρ = 4.43 Mg·m−3
Crystallographic Data
Cell Parameters
Atom Coordinates
Standardized
Published
Displacement Parameters
Isotropic
Experimental Details
Reference
3D Interactive Structure
About this content
PAULING FILE Multinaries Edition – 2012
sd_1212662
©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016
Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland
SpringerMaterials Release 2016.
Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS
All Rights Reserved. Version 2016.10.
Project Coordinator: Shuichi Iwata
Section-Editor: Karin Cenzual (Crystal Structures)
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