Inorganic Solid Phases

K10Na3[PdO(OH)WO(OH2)(PW9O34)2]·17H2O (K10Na3W19Pd[PO4]2O62[OH][H2O]18, T = 173(2) K) Crystal Structure

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General Information

  • Phase Label(s): K10Na3W19Pd[PO4]2O62[OH][H2O]18
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: aP266
  • Space Group: 2
  • Phase Prototype: K10Na3W19Pd[PO4]2O62[OH][H2O]18
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS D8 SMART APEX (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 173(2) K (determination of cell and structural parameters)
  • Phase Class(es): –
  • Compound Class(es): hydroxide, orthophosphate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined; temperature dependence studied, full-matrix least-squares refinement on F2; 703 variables; 21214 reflections, R = 0.0615; wR = 0.1303
  • Sample Detail(s): sample prepared from PdSO4, [A-α-PW9O34]9−, chemical analysis; < 0.01 wt.% Cl, 6.92 wt.% K, 1.25 wt.% Na, 1.15 wt.% P, 1.91 wt.% Pd, 62.6 wt.% W, single crystal (determination of cell parameters), single crystal, 0.04×0.13×0.20 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K10Na3W19Pd[PO4]2O62[OH][H2O]18
  • Alphabetic Formula: [H2O]18K10Na3O62[OH][PO4]2PdW19
  • Published Formula: K10Na3[PdO(OH)WO(OH2)(PW9O34)2]·17H2O
  • Refined Formula: H38.50K10Na3O89P2PdW19
  • Wyckoff Sequence: 2,i133
  • Z Formula Units: 2
  • Density: ρ = 4.33 Mg·m−3
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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1215978

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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