Mn3[Fe(CN)6]2·14H2O (MnFe0.67[CN]4[H2O]4.67) Crystal Structure
General Information
- Phase Label(s): MnFe0.67[CN]4[H2O]4.67
- Structure Class(es): Nasicon family, Prussian blue
- Classification by Properties: –
- Mineral Name(s): –
- Pearson Symbol: cF140
- Space Group: 225
- Phase Prototype: MnFe0.67[CN]4[H2O]4.33
- Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Siemens D5000 (determination of structural parameters), X-rays, Cu Kα (determination of cell and structural parameters)
- Phase Class(es): –
- Compound Class(es): cyanide, hydrate
- Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement; 21 variables, RP = 0.093; wRP = 0.119; RB = 0.131
- Sample Detail(s): sample prepared from ferricyanic acid, MnSO4, thermogravimetry, X-ray fluorescence spectroscopy; H2O content analyzed, Mn3(Fe[CN]6)2[H2O]14; Mn/Fe ratio 3/2, powder (determination of cell and structural parameters)
Substance Summary
- Standard Formula: MnFe0.67[CN]4[H2O]4.67
- Alphabetic Formula: [CN]4Fe0.67[H2O]4.67Mn
- Published Formula: Mn3[Fe(CN)6]2·14H2O
- Refined Formula: C4.02Fe0.67H8.65MnN4.02O4.32
- Wyckoff Sequence: 225,fe4ca
- Z Formula Units: 4
- Density: ρ = 1.62 Mg·m−3
Crystallographic Data
Cell Parameters
Atom Coordinates
Standardized
Published
Displacement Parameters
Isotropic
Experimental Details
Reference
3D Interactive Structure
About this content
PAULING FILE Multinaries Edition – 2012
sd_1228830
©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016
Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland
SpringerMaterials Release 2016.
Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS
All Rights Reserved. Version 2016.10.
Project Coordinator: Shuichi Iwata
Section-Editor: Karin Cenzual (Crystal Structures)
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