Inorganic Solid Phases

Rb6.24Eu1.76In10.16Ge35.84 (Rb3.15Eu0.85In4.88Ge18.12, T = 200 K) Crystal Structure

General Information

  • Phase Label(s): Rb3.15Eu0.85In4.88Ge18.12
  • Structure Class(es): clathrate
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cP54
  • Space Group: 223
  • Phase Prototype: K3Eu(Ga0.22Ge0.78)23
  • Measurement Detail(s): automatic diffractometer; 1027 (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 200 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): intermetallic
  • Interpretation Detail(s): complete structure determined, least-squares refinement; 20 variables; 272 reflections; I > 2σ(I), R = 0.0206; wR = 0.0414
  • Sample Detail(s): sample prepared from Eu, Rb, In, Ge, energy-dispersive X-ray analysis; composition confirmed, single crystal (determination of cell parameters), single crystal, 0.04×0.04×0.05 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Rb3.12Eu0.88In5.08Ge17.92
  • Alphabetic Formula: Eu0.88Ge17.92In5.08Rb3.12
  • Published Formula: Rb6.24Eu1.76In10.16Ge35.84
  • Refined Formula: Eu0.88Ge17.92In5.08Rb3.12
  • Wyckoff Sequence: 223,kidca
  • Z Formula Units: 2
  • Density: ρ = 5.61 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1232723

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied