Inorganic Solid Phases

[Cd(NH3)4]3[W4Te4(CN)12] (Cd3W4Te4[CN]12[NH3]12) Crystal Structure

General Information

  • Phase Label(s): Cd3W4Te4[CN]12[NH3]12
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cP94
  • Space Group: 218
  • Phase Prototype: Zn3Mo4Te4[CN]12[NH3]12
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide, telluride
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 588 reflections; I > 2σ(I), R = 0.0243; wR = 0.0390
  • Sample Detail(s): sample prepared from K6(W4Te4[CN]12)[H2O]5, Cd[NO3]2, chemical analysis; 6.95 wt.% C, 1.83 wt.% H, 16.22 wt.% N, 14.84 wt.% Cd, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Cd3W4Te4[CN]12[NH3]12
  • Alphabetic Formula: [CN]12Cd3[NH3]12Te4W4
  • Published Formula: [Cd(NH3)4]3[W4Te4(CN)12]
  • Refined Formula: C12Cd3H36N24Te4W4
  • Wyckoff Sequence: 218,i3e2d
  • Z Formula Units: 2
  • Density: ρ = 3.32 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1233161

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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