Inorganic Solid Phases

Bi2O(SO4)(OH)2 (Bi2[SO4]O[OH]2) Crystal Structure

General Information

  • Phase Label(s): Bi2[SO4]O[OH]2
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): cannonite
  • Pearson Symbol: mP40
  • Space Group: 14
  • Phase Prototype: Bi2[SO4]O[OH]2
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; FEI Tecnai G2 F30 ST (determination of structural parameters), electrons; λ = 0.00197 nm (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, sulfate, oxide
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; 41 variables; 262 reflections; I > 4σ(I), R = 0.2980; wR = 0.5709
  • Sample Detail(s): cannonite sample from Italy, Crodo, Alfenza mine, energy-dispersive X-ray analysis; Bi/S ratio 2.06, single crystal (determination of cell parameters), single crystal, 0.0003×0.0004×0.00005 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Bi2[SO4]O[OH]2
  • Alphabetic Formula: Bi2O[OH]2[SO4]
  • Published Formula: Bi2O(SO4)(OH)2
  • Refined Formula: Bi2H2O7S
  • Wyckoff Sequence: 14,e10
  • Z Formula Units: 4
  • Density: ρ = 6.53 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1235056

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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