Inorganic Solid Phases

Bi3+Sb5+O4 (BiSbO4, T = 418 K) Crystal Structure

General Information

  • Phase Label(s): BiSbO4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): kyawthuite
  • Pearson Symbol: mS24
  • Space Group: 15
  • Phase Prototype: BiSbO4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Rigaku R-AXIS RAPID II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071075 nm (determination of cell and structural parameters), T = 293 K (determination of cell parameters), T = 418 K (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement on F2; 32 variables; 593 reflections; F > 4σ(F), R = 0.0269; wR = 0.0536
  • Sample Detail(s): kyawthuite sample from Myanmar (Burma), Mogok, Chaung-gyi (Big Stream) valley, electron microprobe analysis; (Bi3+0.82Sb3+0.18)(Sb5+0.99Ta5+0.01)O4, single crystal (determination of cell parameters), single crystal, 0.030×0.030×0.030 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: BiSbO4
  • Alphabetic Formula: BiO4Sb
  • Published Formula: Bi3+Sb5+O4
  • Refined Formula: Bi0.80O4Sb1.20
  • Wyckoff Sequence: 15,f2ec
  • Z Formula Units: 4
  • Density: ρ = 8.45 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Powder Pattern

published defraction line
d [Å]
computed diffraction line for Cu Kα
d [nm]
intensity
I [1]
h [1]
k [1]
l [1]
Radiation
Remark

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1243766

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied