Inorganic Solid Phases

Lch 132 (K0.95Na0.05Li1.58Mn0.04Fe0.01Al2.08Si3.29O10[OH]0.42F1.58 2M) Crystal Structure

General Information

  • Phase Label(s): K0.95Na0.05Li1.58Mn0.04Fe0.01Al2.08Si3.29O10[OH]0.42F1.58 2M
  • Structure Class(es): mica family
  • Classification by Properties:
  • Mineral Name(s): polylithionite/trilithionite 2M2
  • Pearson Symbol: mS80
  • Space Group: 15
  • Phase Prototype: Rb0.05K0.88Na0.06Li1.79Ca0.01Al1.31(Al0.16Si0.84)4O10([OH]0.25F0.75)2
  • Measurement Detail(s): automatic diffractometer; 100 (determination of cell parameters), automatic diffractometer; Siemens P4P (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, silicate, fluoride
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; I > 3σ(I), R = 0.031
  • Sample Detail(s): sample from France, Haute-Vienne, Monts d'Ambazac, Chèdeville, energy-dispersive X-ray analysis; Si3.293Al2.064Ti0.003Fe2+0.008Mn0.044Li1.572Ca0.002Na0.045K0.903[OH]0.412F1.588O10, single crystal (determination of cell parameters), single crystal, 0.09×0.10×0.16 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K0.95Na0.05Li1.58Mn0.04Fe0.01Al2.08Si3.29O10[OH]0.42F1.58
  • Alphabetic Formula: Al2.08F1.58Fe0.01K0.95Li1.58Mn0.04Na0.05O10[OH]0.42Si3.29
  • Published Formula: Lch 132
  • Refined Formula: Al2.08F1.58Fe0.01H0.42K0.95Li1.58Mn0.04Na0.05O10.42Si3.29
  • Wyckoff Sequence: 15,f9ec
  • Z Formula Units: 4
  • Density: ρ = 2.81 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1322065

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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