Inorganic Solid Phases

Na₁₀(WZn(Rh^/// H₂O)₂)(ZnW₉O₃₄)₂·42H₂O (Na₁₀Zn₃W₁₉Rh₂O₆₈[H₂O]₄₄) Crystal Structure

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General Information

Phase Label(s): Na₁₀Zn₃W₁₉Rh₂O₆₈[H₂O]₄₄
Structure Class(es): –
Classification by Properties: –
Mineral Name(s): –
Pearson Symbol: mP292
Space Group: 14
Phase Prototype: Na₁₀Zn₃W₁₉Rh₂O₆₈[H₂O]₄₄
Measurement Detail(s): automatic diffractometer; 24 (determination of cell parameters), automatic diffractometer; Philips PW1100 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters)
Phase Class(es): –
Compound Class(es): oxide, hydrate
Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; 6544 reflections; I > 3σ(I), R = 0.050; wR = 0.069
Sample Detail(s): sample prepared from Na₁₂Zn₃[H₂O]₂Zn₃W₁₉O₆₈[H₂O]₄₆, NaNO₃, RhCl₃[H₂O]₃, single crystal (determination of cell and structural parameters)

Substance Summary

Standard Formula: Na₁₀Zn₃W₁₉Rh₂O₆₈[H₂O]₄₄
Alphabetic Formula: [H₂O]₄₄Na₁₀O₆₈Rh₂W₁₉Zn₃
Published Formula: Na₁₀(WZn(Rh^/// H₂O)₂)(ZnW₉O₃₄)₂·42H₂O
Refined Formula: H₈₈Na₁₀O₁₁₂Rh₂W₁₉Zn₃
Wyckoff Sequence: 14,e⁷³
Z Formula Units: 2
Density: ρ = 4.03 Mg·m⁻³

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Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
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a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
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Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
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Displacement Parameters

Isotropic

Site	Published B [nm²]	Type	Computed B_eq [nm²]
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Experimental Details

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Reference

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3D Interactive Structure

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About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1322696

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials Na10(WZn(Rh/// H2O)2)(ZnW9O34)2·42H2O (Na10Zn3W19Rh2O68[H2O]44) Crystal Structure sd_1322696 (Springer-Verlag GmbH, Heidelberg, © 2016)

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