Inorganic Solid Phases

[Pt(NH3)4][PtBr2(NH3)4](HSO4)4 (H2Pt[SO4]2Br[NH3]4, T = 269 K) Crystal Structure

General Information

  • Phase Label(s): H2Pt[SO4]2Br[NH3]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP34
  • Space Group: 14
  • Phase Prototype: H2Pt[SO4]2Cl[NH3]4
  • Measurement Detail(s): automatic diffractometer; 50 (determination of cell parameters), automatic diffractometer; Rigaku AFC5 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 269 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): sulfate, bromide
  • Interpretation Detail(s): complete structure determined; temperature dependence studied, block-diagonal least-squares refinement; 1448 reflections; F > 3σ(F), R = 0.029
  • Sample Detail(s): sample prepared from Br2, KBrO3, H2O2, Na2S2O3, H2SO4, Pt[NH3]4[PrBr4], Br3.24H46.93N13.55O26.35Pt3.16S6.77, single crystal (determination of cell parameters), single crystal, 0.10×0.22×0.38 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: H2Pt[SO4]2Br[NH3]4
  • Alphabetic Formula: BrH2[NH3]4Pt[SO4]2
  • Published Formula: [Pt(NH3)4][PtBr2(NH3)4](HSO4)4
  • Refined Formula: BrH14N4O8PtS2
  • Wyckoff Sequence: 14,e8a
  • Z Formula Units: 2
  • Density: ρ = 2.96 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1401945

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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