Inorganic Solid Phases

SnAPO-5, ~4% Sn in framework, 2.3% Cu (Cu0.023Al0.48Sn0.04P0.48O2.023) Crystal Structure

General Information

  • Phase Label(s): Cu0.023Al0.48Sn0.04P0.48O2.023
  • Structure Class(es): zeolite AFI
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hP184
  • Space Group: 192
  • Phase Prototype: Cu0.023Al0.48Sn0.04P0.48O2.023
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; United Kingdom, Cheshire, Daresbury Synchrotron Radiation Source, 9.1 station (determination of structural parameters), X-rays, synchrotron; λ = 0.04247 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): phosphate
  • Interpretation Detail(s): complete structure determined, Rietveld refinement; 44 variables; 3401 reflections, RP = 0.0334; wRP = 0.0418; RB = 0.0055
  • Sample Detail(s): sample prepared from triethylamine, SnCl4[H2O]5, AlOOH, H3PO4, CuNO3, electron microprobe analysis; amounts of SnO2 (0.2 wt.%) and AlPO-tridymite (6.3 wt.%), powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Cu0.023Al0.48Sn0.04P0.48O2.023
  • Alphabetic Formula: Al0.48Cu0.023O2.023P0.48Sn0.04
  • Published Formula: SnAPO-5, ~4% Sn in framework, 2.3% Cu
  • Refined Formula: Al0.46Cu0.01O2.20P0.46Sn0.04
  • Wyckoff Sequence: 192,m5l2k2jd
  • Z Formula Units: 24
  • Density: ρ = 1.93 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1410905

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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