Inorganic Solid Phases

[M(NH3)5Cl](ReO4)2, M= Rh (Rh[ReO4]2Cl[NH3]5) Crystal Structure

General Information

  • Phase Label(s): Rh[ReO4]2Cl[NH3]5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oS136
  • Space Group: 36
  • Phase Prototype: Rh[ReO4]2Cl[NH3]5
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS P4 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): tetraoxorhenate(VII), chloride
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 170 variables; I > 2σ(I), R = 0.0213; wR = 0.0510
  • Sample Detail(s): sample prepared from (Rh[NH3]5Cl)Cl2, NaReO4, chemical analysis; 65.9(2) wt.% metal atoms, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Rh[ReO4]2Cl[NH3]5
  • Alphabetic Formula: Cl[NH3]5[ReO4]2Rh
  • Published Formula: [M(NH3)5Cl](ReO4)2, M= Rh
  • Refined Formula: ClH15N5O8Re2Rh
  • Wyckoff Sequence: 36,b13a8
  • Z Formula Units: 8
  • Density: ρ = 3.52 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1421140

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied