Inorganic Solid Phases

NH4[Cu(NH3)4](ClO4)3·NH3 ([NH4]Cu[ClO4]3[NH3]5) Crystal Structure

General Information

  • Phase Label(s): [NH4]Cu[ClO4]3[NH3]5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: tP44
  • Space Group: 113
  • Phase Prototype: [NH4]Cu[ClO4]3[NH3]5
  • Measurement Detail(s): photographs (determination of cell parameters), Weissenberg photographs (determination of structural parameters), X-rays (determination of cell parameters), X-rays, Cu Kα (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): perchlorate
  • Interpretation Detail(s): positions of non-H atoms determined, trial-and-error
  • Sample Detail(s): sample prepared from Cu[NO3]2, NH4ClO4, NH4[OH], chemical analysis; 13.7 wt.% Cu, 21.92 wt.% NH3, 62.35 wt.% ClO4, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: [NH4]Cu[ClO4]3[NH3]5
  • Alphabetic Formula: [ClO4]3Cu[NH3]5[NH4]
  • Published Formula: NH4[Cu(NH3)4](ClO4)3·NH3
  • Refined Formula: Cl3CuH19N6O12
  • Wyckoff Sequence: 113,f2e5c2ba
  • Z Formula Units: 2
  • Density: ρ = 1.84 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1503779

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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