Inorganic Solid Phases

Ba8ZnNb5.1Sb0.9O24 (Ba6Zn0.75Nb3.825Sb0.675O18) Crystal Structure

General Information

  • Phase Label(s): Ba6Zn0.75Nb3.825Sb0.675O18
  • Structure Class(es):
  • Classification by Properties: luminescent, nonmetal
  • Mineral Name(s):
  • Pearson Symbol: hP120
  • Space Group: 185
  • Phase Prototype: Ba6Zn0.75(Nb0.85Sb0.15)4.5O18
  • Measurement Detail(s): automatic diffractometer; Australia, Lucas Heights, Australian Nuclear Science and Technology Organisation, OPAL reactor, ECHIDNA (determination of structural parameters), neutrons; λ = 0.16220 nm (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, Rietveld refinement, multiphase, wRP = 0.0451; RB = 0.0231
  • Sample Detail(s): sample prepared from BaCO3, ZnO, Nb2O5, Sb2O5, chemical analysis; Ba/Zn/Nb/Sb ratio 8/0.92/5.3/0.93; amounts of Ba3ZnNb2O9 (2.5 wt.%), powder (determination of structural parameters)

Substance Summary

  • Standard Formula: Ba6Zn0.75Nb3.825Sb0.675O18
  • Alphabetic Formula: Ba6Nb3.825O18Sb0.675Zn0.75
  • Published Formula: Ba8ZnNb5.1Sb0.9O24
  • Refined Formula: Ba6Nb3.83O18Sb0.67Zn0.75
  • Wyckoff Sequence: 185,d4c9b3a3
  • Z Formula Units: 4
  • Density: ρ = 6.33 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1530359

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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