Inorganic Solid Phases

K1.5(NH4)4.5[MnMo9O32]·4.2H2O (K1.5[NH4]4.5Mo9MnO32[H2O]4.2) Crystal Structure

General Information

  • Phase Label(s): K1.5[NH4]4.5Mo9MnO32[H2O]4.2
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR171
  • Space Group: 146
  • Phase Prototype: K1.5[NH4]4.5Mo9MnO32[H2O]4.2
  • Measurement Detail(s): automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of structural parameters), T = 293 K (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide, hydrate
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 163 variables; 2267 reflections, R = 0.031; wR = 0.088
  • Sample Detail(s): sample prepared from KMnO4, [NH4]6Mo7O24[H2O]4, C6H9N3O2, single crystal, 0.1×0.12×0.15 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K1.5[NH4]4.5Mo9MnO32[H2O]4.2
  • Alphabetic Formula: [H2O]4.2[NH4]4.5K1.5MnMo9O32
  • Published Formula: K1.5(NH4)4.5[MnMo9O32]·4.2H2O
  • Refined Formula: H26.40K1.50MnMo9N4.50O36.20
  • Wyckoff Sequence: 146,b18a3
  • Z Formula Units: 3
  • Density: ρ = 2.99 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1531022

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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