Inorganic Solid Phases

Na13(Ca3Mn3)Zr3(Fe,Mn)3()(Si)[Si3O9]2[Si9O27]2(O,OH,Cl)3·2H2O (Na15.9Ca3.8Zr4Mn0.9Fe2.2Si25.4Cl0.9O73[OH]2.6[H2O]1.1) Crystal Structure

General Information

  • Phase Label(s): Na15.9Ca3.8Zr4Mn0.9Fe2.2Si25.4Cl0.9O73[OH]2.6[H2O]1.1
  • Structure Class(es): eudialyte family
  • Classification by Properties:
  • Mineral Name(s): eudialyte
  • Pearson Symbol: hR486
  • Space Group: 146
  • Phase Prototype: Na16.1Sr0.45Ca2.10Ce1.15Zr3.45Nb0.45Mn3.75Si25.55O74.54[OH]1.27[H2O]2
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Enraf-Nonius (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, silicate, chloride, hydrate
  • Interpretation Detail(s): part of atom coordinates determined, least-squares refinement; F > 5σ(F), R = 0.068
  • Sample Detail(s): eudialyte sample from Canada, Quebec, Rouville County, Mt. Saint-Hilaire, sample prepared from Na13(Ca3Mn3)Zr3(Fe,Mn)3()(Si)[Si3O9]2[Si9O27]2(O,OH,Cl)3[H2O]2, electron microprobe analysis; Na11.45−12.23Ca2.37−2.44REE0.6−0.7K0.1−0.15Zr2.91−3.01Fe0.6−1.12Mn3.51−3.26Nb0.3−0.44Ti0.05−0.07W0.01−0.06Si25.51−25.61O72Cl0.65−0.76Fe0.08−0.26, single crystal (determination of cell parameters), single crystal, 0.2×0.2×0.2 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Na14Ca3Zr3Mn4.5Fe1.5Si25Cl0.35O71[OH]3.15[H2O]2
  • Alphabetic Formula: Ca3Cl0.35Fe1.5[H2O]2Mn4.5Na14O71[OH]3.15Si25Zr3
  • Published Formula: Na13(Ca3Mn3)Zr3(Fe,Mn)3()(Si)[Si3O9]2[Si9O27]2(O,OH,Cl)3·2H2O
  • Refined Formula:
  • Wyckoff Sequence: 146,b15a11
  • Z Formula Units: 3
  • Density:

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1620687

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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