Inorganic Solid Phases

γ-Na_xCoO₂ (x~ 0.58) (Na_4.06Co₇O₁₄ lt1) Crystal Structure

Get Access CIF Download help (pdf)

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

General Information

Phase Label(s): Na_4.06Co₇O₁₄ lt1
Structure Class(es): –
Classification by Properties: Pauli paramagnet, intermediate valence, metal
Mineral Name(s): –
Pearson Symbol: hP50
Space Group: 176
Phase Prototype: K₄Co₇O₁₄
Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Japan, Tokai, Japan Atomic Energy Research Institute, JRR-3M reactor, HERMES (determination of structural parameters), neutrons; λ = 0.18265 nm (determination of cell and structural parameters), T = 280 K (determination of cell and structural parameters)
Phase Class(es): –
Compound Class(es): oxide
Interpretation Detail(s): complete structure determined; temperature dependence studied, Rietveld refinement, wR_P = 0.0583
Sample Detail(s): sample prepared from Na₂CO₃, Co₃O₄, electron microprobe analysis; composition confirmed, powder (determination of cell and structural parameters)

Substance Summary

Standard Formula: Na_4.06Co₇O₁₄
Alphabetic Formula: Co₇Na_4.06O₁₄
Published Formula: γ-Na_xCoO₂ (x~ 0.58)
Refined Formula: Co₇Na₄O₁₄
Wyckoff Sequence: 176,i³hfba
Z Formula Units: 2
Density: ρ = 4.55 Mg·m⁻³

View 3D Interactive Structure

Cite this page

Citation

Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
Space Group	Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Displacement Parameters

Isotropic

Site	Published B [nm²]	Type	Computed B_eq [nm²]
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Experimental Details

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

Reference

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

3D Interactive Structure

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1627139

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials γ-NaxCoO2 (x~ 0.58) (Na4.06Co7O14 lt1) Crystal Structure sd_1627139 (Springer-Verlag GmbH, Heidelberg, © 2016)

Download this citation

Citation copied