Inorganic Solid Phases

Bi₂₄(Bi_0.130(3)Si_0.277(3)Mn_1.593(3))O₄₀, Bi₂₄(Si_xMn_1−x)₂O₄₀ (Mn_0.5Bi₁₂Si_0.5O₂₀) Crystal Structure

Get Access CIF Download help (pdf)

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

General Information

Phase Label(s): Mn_0.5Bi₁₂Si_0.5O₂₀
Structure Class(es): –
Classification by Properties: –
Mineral Name(s): –
Pearson Symbol: cI66
Space Group: 197
Phase Prototype: Bi₁₂SiO₂₀
Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 298 K (determination of structural parameters)
Phase Class(es): –
Compound Class(es): silicate
Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 30 variables; 575 reflections; F² > 3σ(F²), R = 0.110; wR = 0.125
Sample Detail(s): sample prepared from NaBiO₃, Na₂SiO₃, Mn[NO₃]₂, single crystal (determination of cell parameters), single crystal, 0.17×0.17×0.17 mm³ (determination of structural parameters)

Substance Summary

Standard Formula: Mn_0.80Bi_12.07Si_0.14O₂₀
Alphabetic Formula: Bi_12.07Mn_0.80O₂₀Si_0.14
Published Formula: Bi₂₄(Bi_0.130(3)Si_0.277(3)Mn_1.593(3))O₄₀, Bi₂₄(Si_xMn_1−x)₂O₄₀
Refined Formula: Bi_12.01Mn_0.91O₂₀Si_0.08
Wyckoff Sequence: 197,f²c²a
Z Formula Units: 2
Density: ρ = 9.20 Mg·m⁻³

View 3D Interactive Structure

Cite this page

Citation

Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
Space Group	Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Displacement Parameters

Isotropic

Site	Published U [nm²]	Type	Computed B_eq [nm²]
Content available to subscribers To view content, please Log in, contact your Springer representative, or get a free trial

Experimental Details

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

Reference

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

3D Interactive Structure

Content available to subscribers
To view content, please Log in, contact your Springer representative, or get a free trial

About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1630181

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials Bi24(Bi0.130(3)Si0.277(3)Mn1.593(3))O40, Bi24(SixMn1−x)2O40 (Mn0.5Bi12Si0.5O20) Crystal Structure sd_1630181 (Springer-Verlag GmbH, Heidelberg, © 2016)

Download this citation

Citation copied