Inorganic Solid Phases

Eu[Fe(CN)6]·4H2O (EuFe[CN]6[H2O]4) Crystal Structure

General Information

  • Phase Label(s): EuFe[CN]6[H2O]4
  • Structure Class(es):
  • Classification by Properties: antiferromagnet AFM
  • Mineral Name(s):
  • Pearson Symbol: oS72
  • Space Group: 63
  • Phase Prototype: SmFe[CN]6[H2O]4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Japan, Hyogo, Japan Synchrotron Radiation Research Institute, SPring-8, BL02B2 (determination of structural parameters), X-rays, synchrotron; λ = 0.06003 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement, RP = 0.04419; wRP = 0.06096; RB = 0.0226
  • Sample Detail(s): sample prepared from Eu[NO3]3[H2O]6, K3Fe[CN]6, chemical analysis, inductive coupled plasma method; 34.8 wt.% Eu, 12.7 wt.% Fe, 16.46 wt.% C, 18.89 wt.% N, 1.76 wt.% H, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: EuFe[CN]6[H2O]4
  • Alphabetic Formula: [CN]6EuFe[H2O]4
  • Published Formula: Eu[Fe(CN)6]·4H2O
  • Refined Formula: C6EuFeH8N6O4
  • Wyckoff Sequence: 63,h2gf3ca
  • Z Formula Units: 4
  • Density: ρ = 2.23 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1641119

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied