Inorganic Solid Phases

Na15H[{Zn(II)SiW8O31}2]·49H2O (HNa15Zn2W16[SiO4]2O54[H2O]49, T = 150(2) K) Crystal Structure

Get Access CIF Download help (pdf)

General Information

  • Phase Label(s): HNa15Zn2W16[SiO4]2O54[H2O]49
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: aP166
  • Space Group: 2
  • Phase Prototype: HNa15Zn2W16[SiO4]2O54[H2O]49
  • Measurement Detail(s): automatic diffractometer; 9374 (determination of cell parameters), automatic diffractometer; Bruker AXS APEX II QUAZAR (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 150(2) K (determination of cell and structural parameters)
  • Phase Class(es): –
  • Compound Class(es): orthosilicate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 658 variables; 8685 reflections; I > 2σ(I), R = 0.0278; wR = 0.0759
  • Sample Detail(s): sample prepared from ZnCl2, (1,4-bis(2-hydroxyethyl)piperazine), H2SO4, NaCl, K8[γ-SiW10O36][H2O]12, single crystal (determination of cell parameters), single crystal, 0.101×0.101×0.128 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: HNa15Zn2W16[SiO4]2O54[H2O]49
  • Alphabetic Formula: [H2O]49H[SiO4]2Na15O54W16Zn2
  • Published Formula: Na15H[{Zn(II)SiW8O31}2]·49H2O
  • Refined Formula: H96Na15O110Si2W16Zn2
  • Wyckoff Sequence: 2,i83
  • Z Formula Units: 1
  • Density: ρ = 3.60 Mg·m−3
View 3D Interactive Structure

Cite this page

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1642746

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

    • Cite this content

    Download this citation

    Citation copied