[Co(NH3)5Cl](ReO4)2·0.25H2O, [Co(NH3)5Cl](ReO4)2·nH2O (Co[ReO4]2Cl[NH3]5[H2O]0.25) Crystal Structure
General Information
- Phase Label(s): Co[ReO4]2Cl[NH3]5[H2O]0.25
- Structure Class(es): –
- Classification by Properties: –
- Mineral Name(s): –
- Pearson Symbol: oS140
- Space Group: 36
- Phase Prototype: Co[ReO4]2Cl[NH3]5[H2O]0.25
- Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker-Nonius X8 APEX (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
- Phase Class(es): –
- Compound Class(es): tetraoxorhenate(VII), chloride, hydrate
- Interpretation Detail(s): positions of non-H and part of H atoms determined, full-matrix least-squares refinement on F2; 179 variables; 3211 reflections; I > 2σ(I), R = 0.0215; wR = 0.0453
- Sample Detail(s): sample prepared from (Co[NH3]5Cl)Cl2, NaReO4, chemical analysis; 62.6 wt.% (Co+Re), 2.5 wt.% H, 10.3 wt.% N, single crystal (determination of cell parameters), single crystal, 0.08×0.12×0.25 mm3 (determination of structural parameters)
Substance Summary
- Standard Formula: Co[ReO4]2Cl[NH3]5[H2O]0.25
- Alphabetic Formula: ClCo[H2O]0.25[NH3]5[ReO4]2
- Published Formula: [Co(NH3)5Cl](ReO4)2·0.25H2O, [Co(NH3)5Cl](ReO4)2·nH2O
- Refined Formula: ClCoH15.50N5O8.25Re2
- Wyckoff Sequence: 36,b13a9
- Z Formula Units: 8
- Density: ρ = 3.39 Mg·m−3
Crystallographic Data
Cell Parameters
Atom Coordinates
Standardized
Published
Displacement Parameters
Isotropic
Anisotropic
Experimental Details
Reference
3D Interactive Structure
About this content
PAULING FILE Multinaries Edition – 2012
sd_1719590
©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016
Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland
SpringerMaterials Release 2016.
Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS
All Rights Reserved. Version 2016.10.
Project Coordinator: Shuichi Iwata
Section-Editor: Karin Cenzual (Crystal Structures)
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