Inorganic Solid Phases

hydrated Ni-NaY faujasite; Ni18Na22Y faujasite, water content 0.4, NaY= Na58Al58Si134O384 (Na5.5Ni4.5Al14.5Si33.5O96[H2O]0.1, T = 623 K) Crystal Structure

General Information

  • Phase Label(s): Na5.5Ni4.5Al14.5Si33.5O96[H2O]0.1
  • Structure Class(es): zeolite FAU
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF656
  • Space Group: 227
  • Phase Prototype: Na5.5Ni4.5(Al0.30Si0.70)48O96[H2O]0.1
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; France, Saclay, Laboratoire Léon Brillouin LLB, ORPHEE reactor, G4.1 (determination of structural parameters), neutrons; λ = 0.24226 nm (determination of cell and structural parameters), T = 623 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): silicate, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement; 18 variables, RP = 0.0507; wRP = 0.0688
  • Sample Detail(s): sample prepared from Ni18Na22Al58Si134O384[H2O]91.8, thermogravimetry (TGA), X-ray fluorescence spectroscopy; Ni18Na22Al58Si134O384[H2O]n, n= 0.4, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Na5.5Ni4.5Al14.5Si33.5O96[H2O]0.1
  • Alphabetic Formula: Al14.5[H2O]0.1Na5.5Ni4.5O96Si33.5
  • Published Formula: hydrated Ni-NaY faujasite; Ni18Na22Y faujasite, water content 0.4, NaY= Na58Al58Si134O384
  • Refined Formula: Al14.50Na5.10Ni4.46O96Si33.50
  • Wyckoff Sequence: 227,ihg3e2c
  • Z Formula Units: 4
  • Density: ρ = 1.49 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1725038

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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