Inorganic Solid Phases

Bi₄(V_0.85Co_0.15)₂O_11−d (V_0.9Co_0.1Bi₂O_5.35 rt) Crystal Structure

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General Information

Phase Label(s): V_0.9Co_0.1Bi₂O_5.35 rt
Structure Class(es): –
Classification by Properties: –
Mineral Name(s): –
Pearson Symbol: tI42
Space Group: 139
Phase Prototype: (V_0.85Mn_0.15)Bi₂O_5.35
Measurement Detail(s): automatic diffractometer; 24 (determination of cell parameters), automatic diffractometer; France, Grenoble, Centre d'Etudes Nucléaires CEN, SILOE reactor, DN4 (determination of structural parameters), neutrons; λ = 0.11811 nm (determination of cell and structural parameters), T = 293 K (determination of cell and structural parameters)
Phase Class(es): –
Compound Class(es): oxide
Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 31 variables; 137 reflections, R = 0.048; wR = 0.067
Sample Detail(s): sample prepared from Bi₂O₃, V₂O₅, CoO, energy-dispersive X-ray analysis; V/Co ratio confirmed, single crystal (determination of cell parameters), single crystal, 4 mm³ (determination of structural parameters)

Substance Summary

Standard Formula: V_0.85Co_0.15Bi₂O_5.312
Alphabetic Formula: Bi₂Co_0.15O_5.312V_0.85
Published Formula: Bi₄(V_0.85Co_0.15)₂O_11−d
Refined Formula: Bi_2.04Co_0.13O_5.31V_0.84
Wyckoff Sequence: 139,n²e²dca
Z Formula Units: 2
Density: ρ = 7.72 Mg·m⁻³

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Crystallographic Data

Cell Parameters

	Published Data	Standardized Data
	Published Data	Unit Cell	Niggli-Reduced Cell
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a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation	Co-ord. No.	Atomic Env.
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Published

Site	Element	Wyckoff Symbol	Symmetry	X	Y	Z	Occupation
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Displacement Parameters

Isotropic

Site	Published U [nm²]	Type	Computed B_eq [nm²]
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Anisotropic

Site	U₁₁ [nm²]	U₂₂ [nm²]	U₃₃ [nm²]	U₁₂ [nm²]	U₁₃ [nm²]	U₂₃ [nm²]
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Experimental Details

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Reference

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3D Interactive Structure

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About this content

Database name

PAULING FILE Multinaries Edition – 2012

Dataset ID

sd_1804904

Copyright

©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

Chief Editor

Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

villars.mpds@bluewin.ch

Credits

SpringerMaterials Release 2016.

Project Coordinator: Shuichi Iwata

Section-Editor: Karin Cenzual (Crystal Structures)

Cite this content

Pierre Villars (Chief Editor), PAULING FILE in: Inorganic Solid Phases, SpringerMaterials (online database), Springer, Heidelberg (ed.) SpringerMaterials Bi4(V0.85Co0.15)2O11−d (V0.9Co0.1Bi2O5.35 rt) Crystal Structure sd_1804904 (Springer-Verlag GmbH, Heidelberg, © 2016)

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Bi4(V0.85Co0.15)2O11−d (V0.9Co0.1Bi2O5.35 rt) Crystal Structure

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General Information

Substance Summary

Cite this page

Crystallographic Data

Cell Parameters

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Atom Coordinates

Standardized

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Published

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Displacement Parameters

Isotropic

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Anisotropic

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Experimental Details

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Reference

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3D Interactive Structure

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About this content

Cite this content

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Bi₄(V_0.85Co_0.15)₂O_11−d (V_0.9Co_0.1Bi₂O_5.35 rt) Crystal Structure