Ru2(O2CCF3)4 (Ru[CF3CO2]2, T = 143 K) Crystal Structure
General Information
- Phase Label(s): Ru[CF3CO2]2
- Structure Class(es): –
- Classification by Properties: –
- Mineral Name(s): –
- Pearson Symbol: aP30
- Space Group: 2
- Phase Prototype: Ru[CF3CO2]2
- Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 143 K (determination of cell and structural parameters)
- Phase Class(es): –
- Compound Class(es): trifluoro-acetate
- Interpretation Detail(s): complete structure determined; temperature dependence studied, full-matrix least-squares refinement on F2; 136 variables; 1792 reflections; I > 2σ(I), R = 0.0275; wR = 0.0698
- Sample Detail(s): sample prepared from Ru2(CH3CO2)4, CF3CO2H, [CF3CO]2O, chemical analysis; 34.27 wt.% F, 30.52 wt.% Ru, 19.78 wt.% O, 14.22 wt.% C, single crystal (determination of cell parameters), single crystal, 0.02×0.03×0.12 mm3 (determination of structural parameters)
Substance Summary
- Standard Formula: Ru[CF3CO2]2
- Alphabetic Formula: [CF3CO2]2Ru
- Published Formula: Ru2(O2CCF3)4
- Refined Formula: C4F6O4Ru
- Wyckoff Sequence: 2,i15
- Z Formula Units: 2
- Density: ρ = 2.70 Mg·m−3
Crystallographic Data
Cell Parameters
Atom Coordinates
Standardized
Published
Displacement Parameters
Isotropic
Anisotropic
Experimental Details
Reference
3D Interactive Structure
About this content
PAULING FILE Multinaries Edition – 2012
sd_1817418
©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016
Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland
SpringerMaterials Release 2016.
Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS
All Rights Reserved. Version 2016.10.
Project Coordinator: Shuichi Iwata
Section-Editor: Karin Cenzual (Crystal Structures)
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