Inorganic Solid Phases

[(NH3)5CoOSeO2]Cl·5/2H2O (Co2[SeO3]2Cl2[NH3]10[H2O]5) Crystal Structure

General Information

  • Phase Label(s): Co2[SeO3]2Cl2[NH3]10[H2O]5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS108
  • Space Group: 15
  • Phase Prototype: Co2[SeO3]2Cl2[NH3]10[H2O]5
  • Measurement Detail(s): automatic diffractometer; Syntex P1 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): trioxoselenate(IV), chloride, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 139 variables; 1342 reflections; F2 > 3σ(F2), R = 0.024; wR = 0.032
  • Sample Detail(s): sample prepared from [NH3]5CoH2OCl3, NH4[OH], Na2SeO3, chemical analysis; Cl3.24Co3.22H57.93N16.33O16.01Se3.26, single crystal, 0.18×0.19×0.23 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Co2[SeO3]2Cl2[NH3]10[H2O]5
  • Alphabetic Formula: Cl2Co2[H2O]5[NH3]10[SeO3]2
  • Published Formula: [(NH3)5CoOSeO2]Cl·5/2H2O
  • Refined Formula: Cl2Co2H40N10O11Se2
  • Wyckoff Sequence: 15,f13e
  • Z Formula Units: 4
  • Density: ρ = 1.95 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1905275

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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