Inorganic Solid Phases

Pb[Fe2(CO)8]2 (Fe4Pb[CO]16) Crystal Structure

General Information

  • Phase Label(s): Fe4Pb[CO]16
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP148
  • Space Group: 14
  • Phase Prototype: Fe4Pb[CO]16
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Syntex P21 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 297 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): carbonyl
  • Interpretation Detail(s): complete structure determined, least-squares refinement; 1824 reflections, R = 0.050; wR = 0.058
  • Sample Detail(s): sample prepared from [(C2H5)4N]2[Pb(Fe2[CO]8)(Fe[CO]4)2], Cu(CH3CN)4[BF4], chemical analysis; 24.57 wt.% Fe, 22.68 wt.% Pb, single crystal (determination of cell parameters), single crystal, 0.10×0.17×0.23 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Fe4Pb[CO]16
  • Alphabetic Formula: [CO]16Fe4Pb
  • Published Formula: Pb[Fe2(CO)8]2
  • Refined Formula: C16Fe4O16Pb
  • Wyckoff Sequence: 14,e37
  • Z Formula Units: 4
  • Density: ρ = 2.32 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1905332

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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