Inorganic Solid Phases

Rb14Li10[(AsW9O33)4(Mo2O2S2(H2O)2)6]·90H2O (Rb7Li5W18Mo6[AsO3]2S6O66[H2O]51) Crystal Structure

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General Information

  • Phase Label(s): Rb7Li5W18Mo6[AsO3]2S6O66[H2O]51
  • Structure Class(es): –
  • Classification by Properties: –
  • Mineral Name(s): –
  • Pearson Symbol: mS1200
  • Space Group: 15
  • Phase Prototype: Rb7Li5W18Mo6[AsO3]2S6O66[H2O]51
  • Measurement Detail(s): automatic diffractometer; 8158 (determination of cell parameters), automatic diffractometer; Bruker-Nonius X8 APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 298(2) K (determination of cell and structural parameters)
  • Phase Class(es): –
  • Compound Class(es): arsenite, oxide, sulfide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 1316 variables; 13445 reflections; I > 2σ(I), R = 0.0588; wR = 0.1731
  • Sample Detail(s): sample prepared from Na1.33Rb4.66([AsW9O33][Mo2O2S2]1.5)[H2O]16, LiCl, chemical analysis; 2.23 wt.% As, 0.40 wt.% Li, 8.96 wt.% Mo, 8.72 wt.% Rb, 3.02 wt.% S, 48.38 wt.% W, single crystal (determination of cell parameters), single crystal, 0.10×0.10×0.14 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Rb7Li5W18Mo6[AsO3]2S6O66[H2O]51
  • Alphabetic Formula: [AsO3]2[H2O]51Li5Mo6O66Rb7S6W18
  • Published Formula: Rb14Li10[(AsW9O33)4(Mo2O2S2(H2O)2)6]·90H2O
  • Refined Formula: As2H39.40Mo6O91.70Rb4.95S6W18
  • Wyckoff Sequence: 15,f149e2
  • Z Formula Units: 8
  • Density: ρ = 3.63 Mg·m−3
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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1935300

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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