Inorganic Solid Phases

Fe0.8Ni1.8Sb0.4O4 (FeNi1.67Sb0.33O4, T = 1.7 K) Crystal Structure

General Information

  • Phase Label(s): FeNi1.67Sb0.33O4
  • Structure Class(es): spinel family
  • Classification by Properties: ferrimagnet FiM, semiconductor
  • Mineral Name(s):
  • Pearson Symbol: cF56
  • Space Group: 227
  • Phase Prototype: MgAl2O4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; France, Saclay, Laboratoire Léon Brillouin LLB, ORPHEE reactor, G4.1 (determination of structural parameters), neutrons; λ = 0.2426 nm (determination of cell and structural parameters), T = 1.7 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; magnetic structure determined; temperature dependence studied, Rietveld refinement, multiphase, RP = 0.0326; wRP = 0.0531; RB = 0.0212
  • Sample Detail(s): sample prepared from NiCO3, Sb2O4.35, Fe2O3 (hematite), energy-dispersive X-ray analysis; Fe/Ni/Sb ratio 0.74(2)/1.84(2)/0.42(2); amounts of NiSb2O6 (< 4 wt.%), powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Fe0.8Ni1.8Sb0.4O4
  • Alphabetic Formula: Fe0.8Ni1.8O4Sb0.4
  • Published Formula: Fe0.8Ni1.8Sb0.4O4
  • Refined Formula: Fe0.74Ni1.84O4Sb0.42
  • Wyckoff Sequence: 227,ecb
  • Z Formula Units: 8
  • Density: ρ = 5.88 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1945713

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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